
The JAL-Z colorimeter is a compact analytical instrumentation for online analysis and process monitoring. The colorimeter is based on a color-developing chemical reaction carried out inside the analyzer's glass cell. The sample, coming from an external reservoir or process stream is autonomously grabbed by the instrument and mixed with the appropriate reagents to make the reaction happen. The analyzer uses an LED light source and a photodiode to photometrically measure the developed color intensity (absorbance). The absorbance is proportional to the concentration of the target chemical species (analite).
The determination ranges of the manganese analyzer vary from trace μg/L to 50 mg/L Mn2+ using the (optional) internal dilution module. Ranges also depend on the colorimetric method used.
The determination of traces of manganese is performed photometrically using LMG method. Manganese in lower valency states is oxidised to form permanganate by the action of an oxidising agent. The formed manganese dioxide is able to oxidize leucomalachite green to malachite green. Malachite green is intensive blue colored when the solution is buffered between pH=4 and pH=5. This blue color (absorbance) intensity is proportional to the manganese concentration in the sample and is measured at 625 nm.
Measured parameter: Mn2+
Range :
(Ø 26 mm) 1 - 50 ppb
(Ø 16 mm) 1 - 100 ppb
(with dilution) 5 ppm
Reproducibility*
(Ø 16 mm) ± 1 ppb / ± 9 %
* if two values take whichever is greater
Limit of detection : 1 ppb
Wavelength : 625 nm
Demineralized water : Not required
Number of reagents: 3
Min. analysis time : 13 minutes
Default analysis time : 20 minutes
Reagent consumption**
(Ø 26 mm) 2 L
(Ø 16 mm) 1 L
** per month, at the default analysis frequency.
The determination of manganese is performed photometrically using PAN method. The PAN reagent is suspended in water by use of a surfactant and forms a color complex with manganese. The absorbance intensity is proportional to the manganese concentration in the sample and is measured at 572 nm.
Measured parameter: Mn2+
Range :
(Ø 26 mm) 1 - 200 ppb
(Ø 16 mm) 5 - 1000 ppb
(with dilution) 50 ppm
Reproducibility*
(Ø 26 mm) ± 3 ppb / ± 5%
(Ø 16 mm) ± 2 ppb / ± 10 %
* if two values take whichever is greater
Limit of detection : 1 ppb
Wavelength : 572 nm
Demineralized water : Not required
Number of reagents: 2
Min. analysis time : 10 minutes
Default analysis time : 20 minutes
Reagent consumption**
(Ø 26 mm) 1.5 L
(Ø 16 mm) 1 L
** per month, at the default analysis frequency.
In alkaline solution manganese reacts with formaldoxime to form an orange-red complex. The intensity of color produced in the test is proportional to the manganese(II) concentration.
Measured parameter: Mn2+
Range :
(Ø 26 mm) 0 - 500 ppb
(Ø 16 mm) 0 - 1000 ppb
(with dilution) 0 - 10 ppm
Reproducibility*
(Ø 16 mm) ± 2 ppb / ± 10 %
* if two values take whichever is greater
Wavelength : 430 nm
Demineralized water : Not required
Number of reagents: 3
Min. analysis time : 7 minutes
Default analysis time : 15 minutes
Reagent consumption**
(Ø 26 mm) 1.5 L
(Ø 16 mm) 1 L
** per month, at the default analysis frequency.
JAL-Z_Chlorine-Colorimeter-Datasheet (pdf)
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